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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">vestiag</journal-id><journal-title-group><journal-title xml:lang="ru">Известия Национальной академии наук Беларуси. Серия аграрных наук</journal-title><trans-title-group xml:lang="en"><trans-title>Proceedings of the National Academy of Sciences of Belarus. Agrarian Series</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1817-7204</issn><issn pub-type="epub">1817-7239</issn><publisher><publisher-name>The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.29235/18177204-2026-64-2-165-176</article-id><article-id custom-type="elpub" pub-id-type="custom">vestiag-864</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ПЕРАПРАЦОЎКА І ЗАХАВАННЕ СЕЛЬСКАГАСПАДАРЧАЙ ПРАДУКЦЫІ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>PROCESSING AND STORAGE OF AGRICULTURAL PRODUCTION</subject></subj-group></article-categories><title-group><article-title>Кинетика и механизм деградации каротиноидов в тыквенном порошке: роль температуры и состава упаковочной атмосферы</article-title><trans-title-group xml:lang="en"><trans-title>Kinetics and mechanism of carotenoid degradation in pumpkin powder: effect of storage temperature and packaging atmosphere</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-3982-9700</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Рожнов</surname><given-names>Е. Д.</given-names></name><name name-style="western" xml:lang="en"><surname>Rozhnov</surname><given-names>E. D.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Рожнов Евгений Дмитриевич – доктор технических наук, профессор кафедры биотехнологии, научный сотрудник лаборатории «АлтайБиоЛакт»</p><p>пр. Ленина, 46, Барнаул, 656038</p></bio><bio xml:lang="en"><p>Evgeny D. Rozhnov – Dr. Sc. (Engineering), Professor of the Department of Biotechnology, Researcher of the La- boratory “AltaiBioLakt”</p><p>46, Lenin Ave., Barnaul, 656038</p></bio><email xlink:type="simple">red.bti@yandex.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-9146-6951</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Школьникова</surname><given-names>М. Н.</given-names></name><name name-style="western" xml:lang="en"><surname>Shkolnikova</surname><given-names>M. N.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Школьникова Марина Николаевна – доктор технических наук, доцент, профессор кафедры биотехнологии, ведущий научный сотрудник лаборатории «АлтайБиоЛакт»</p><p>пр. Ленина, 46, Барнаул, 656038</p></bio><bio xml:lang="en"><p>Marina N. Shkolnikova – Dr. Sc. (Engineering), Associate Professor, Professor of the Department of Biotechnology, Leading Researcher of the Laboratory “AltaiBioLakt”</p><p>46, Lenin Ave., Barnaul, 656038</p></bio><email xlink:type="simple">shkolnikova.m.n@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-4938-8136</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Мусина</surname><given-names>О. Н.</given-names></name><name name-style="western" xml:lang="en"><surname>Musina</surname><given-names>O. N.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Мусина Ольга Николаевна – доктор технических наук, доцент, профессор кафедры технологии продук­ тов питания, главный научный сотрудник лаборатории «АлтайБиоЛакт»</p><p>пр. Ленина, 46, Барнаул, 656038</p></bio><bio xml:lang="en"><p>Olga N. Musina – Dr. Sc. (Engineering), Associate Professor, Professor of the Department of Food Technology, Chief Researcher of the Laboratory “AltaiBioLakt”</p><p>46, Lenin Ave., Barnaul, 656038</p></bio><email xlink:type="simple">musinaolga@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Алтайский государственный технический университет им. И. И. Ползунова</institution></aff><aff xml:lang="en"><institution>Polzunov Altai State Technical University</institution></aff></aff-alternatives><pub-date pub-type="collection"><year>2026</year></pub-date><pub-date pub-type="epub"><day>29</day><month>04</month><year>2026</year></pub-date><volume>64</volume><issue>2</issue><fpage>165</fpage><lpage>176</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Рожнов Е.Д., Школьникова М.Н., Мусина О.Н., 2026</copyright-statement><copyright-year>2026</copyright-year><copyright-holder xml:lang="ru">Рожнов Е.Д., Школьникова М.Н., Мусина О.Н.</copyright-holder><copyright-holder xml:lang="en">Rozhnov E.D., Shkolnikova M.N., Musina O.N.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://vestiagr.belnauka.by/jour/article/view/864">https://vestiagr.belnauka.by/jour/article/view/864</self-uri><abstract><p>Каротиноиды обладают высокой чувствительностью к окислению и термическому разложению, что ограничивает их стабильность в пищевых порошках растительного происхождения. Целью настоящего исследования являлось установление кинетических закономерностей и параметров деградации каротиноидов в порошке ферментолизованного тыквенного пюре при различных температурах хранения (+4, +20 и +30 °С) и газовых средах (вакуум, азот, диоксид углерода и воздух). Содержание каротиноидов отслеживали спектрофотометрически в течение 12 мес. Установлено, что во всех условиях деградация подчиняется кинетике первого порядка (R2 &gt; 0,998). Показано, что наличие кислорода является ключевым фактором окисления: константы скорости деградации в воздухе в 2,4–5,1 раза превышали аналогичные показатели в инертных средах. Энергия активации в инертных атмосферах (48,8–59,4 кДж/моль) оказалась выше, чем в воздухе (41,4 кДж/моль), что указывает на смену механизма деградации с окислительного на термический при удалении кислорода. На основе полученных моделей рассчитаны сроки годности тыквенного порошка (потеря ≤ 20 % каротиноидов): при холодовом хранении (0...+4 °С) предпочтительна упаковка в атмосфере азота или CO2 (срок ~20 мес.), тогда как при возможных температурных отклонениях (до +30 °С) наиболее эффективна вакуумная упаковка (~13 мес. против 9,5–11,0 мес. в инертных средах). Упаковка в воздушной среде не рекомендована: при холодовом хранении срок годности ≤ 7,5 мес., а при комнатной температуре ~2,5 мес. Практическая значимость работы заключается в научном обосновании выбора упаковки: для длительного хранения с риском температурных колебаний рекомендована вакуумная упаковка, а для гарантированного холодового хранения – упаковка в атмосфере азота или диоксида углерода.</p></abstract><trans-abstract xml:lang="en"><p>Carotenoids are highly susceptible to oxidative and thermal degradation, which compromises the nutritional and functional quality of plant-based food powders. This study aimed to establish the kinetic parameters governing carotenoid degradation in enzyme-hydrolyzed pumpkin powder under varying storage temperatures (4, 20, and 30 °C) and gas atmospheres (vacuum, nitrogen, carbon dioxide, and ambient air). Carotenoid content was monitored spectrophotometrically over 12 months, and degradation kinetics were modeled using first-order reaction kinetics and the Arrhenius equation. The degradation process followed first-order kinetics in all conditions (R2 &gt; 0.998). Oxygen presence dramatically accelerated carotenoid loss: degradation rate constants in air were 2.4–5.1 times higher than in inert or vacuum environments. Activation energies (Eₐ) were significantly higher in oxygen-free systems (48.8–59.4 kJ/mol) compared to air (41.4 kJ/mol), indicating a shift from oxidation-driven to thermally driven degradation mechanisms. Based on the kinetic models, shelf life (defined as 20 % carotenoid loss) was predicted across temperature – atmosphere combinations. For cold-chain storage (0...4 °C), nitrogen or CO2 packaging provided the longest shelf life (~20 months), whereas vacuum packaging proved superior under temperature abuse (e.g., 30 °C), extending shelf life to ~13 months versus 2.5–7.5 months in air. The practical significance of this work lies in providing a scientific basis for packaging selection: vacuum packaging is recommended for long-term storage, especially with the risk of temperature fluctuations, while packaging under a nitrogen or carbon dioxide atmosphere is optimal for guaranteed cold chain storage.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>каротиноиды</kwd><kwd>кинетика деградации</kwd><kwd>уравнение Аррениуса</kwd><kwd>модифицированная газовая среда</kwd><kwd>тыквенный порошок</kwd><kwd>срок годности</kwd></kwd-group><kwd-group xml:lang="en"><kwd>carotenoids</kwd><kwd>degradation kinetics</kwd><kwd>Arrhenius equation</kwd><kwd>modified atmosphere packaging</kwd><kwd>pumpkin powder</kwd><kwd>shelf life</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Данное исследование проведено в рамках выполнения государственного задания Министерства науки и высшего образования Российской Фе- дерации (№ 075-03-2024-105; тема № FZMM-2024-0003; рег. № НИОКТР 124013000666-5).</funding-statement><funding-statement xml:lang="en">This work was carried out within the framework of the state assignment of the Ministry of Science and Higher Education of the Russian Federation (Project No. 075-03-2024-105; Topic No. FZMM-2024-0003; State Registration No. 124013000666-5).</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Nikolaeva M. 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